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Amine Catalyst
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A-1 contains 70% bis(2-dimethylamino ethyl) ether,
one of the most active urethane foam |
amine catalysts known. As a matter of convenience, the
pure amine ether has been diluted with 30 weight percent
dipropylene glycol to facilitate metering and to permit
the use of conventional quantities in foam formulations.
| Properties |
Specification |
Specific Gravity (20/20ˇÉ)
Viscosity (20ˇÉ, cP)
Freezing Point
Vapor Pressure, mm Hg |
0.9022
4.1
Sets to glass below -80(-112˘µ)
0.01 |
Solubility in Water(20ˇÉ)
Solubility in Benzene
Refractive Index, nD(25ˇÉ) |
Complete
Complete
1.4346 |
Flash Point ˇÉ[˘µ]
Pensky-Martens Closed Cup
Cleveland Open Cup |
74[165]
77[170] |
| ˘şCatalytic Activity |
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The basic chemical reactions important
in the polyether foaming process are
the |
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| poly/isocyanate reaction and the water/isocyanate
reaction. In the polyol/isocyanate (alcohol/isocyanate)reaction,
catalyst A-1 give a specific rate constant
thhat is about 10 percent higher than a similar
blend of triethylenediamine, the next most
active amine. In the water/isocyanate reaction,
however, A-1 has a specific rate constant
that is 50% greater than triethylenediamine,
the next most active amine. |
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The strong catalytic effect of A-1
toward the water/isocyanate reaction
facilitates the |
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| balancing of the catalysis of the polyol/isocyanate
reaction by small variations in the stannous
octoate level. This control is important in
the production of commercial open-celled,
split-free, flexible-urethane foam. The level
of A-1 can be adjusted over a wide range to
permit control of foam rise time without a
sacrifice in tin operating range. |
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